Manufacture of electrodes

Batteries available here in record time

With a new coating process, a research team at the Karlsruhe Institute of Technology (KIT) has succeeded in producing electrodes for lithium-ion batteries at the fastest rate to date. At the same time, the new process improves the quality of the electrodes and reduces production costs.

Precise edges at a new record speed: New process increases production capacity of battery electrodes. © Ralf Diehm, KIT

In the manufacture of electrodes for batteries, electrode material is applied as a thin paste in a rectangular pattern to a foil made of copper or aluminum. The pattern is interrupted by short sections of uncoated foil, which are essential for discharging the electrons. For these sections, the coating process must be interrupted and restarted repeatedly. A particular challenge here is to enable sharp edges without smearing the material at very high production speeds.

"Precision in electrode coating is a very important factor for the efficiency and costs of the entire battery cell production process," says Professor Wilhelm Schabel from the Institute of Thermal Process Engineering - Thin Film Technology (TVT-TFT), who is responsible for research on this topic at KIT. "Even small production errors make battery cells unusable. Due to the high level of waste and low throughput, lithium-ion batteries are now more expensive than they actually need to be." It is precisely this area that enables the greatest cost savings in cell production, emphasizes Schabel.

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Faster coating using a membrane nozzle
PhD student Ralf Diehm in Schabel's group has now made a decisive advancement. He has equipped and further developed the nozzle for the electrode material with an oscillating membrane that cyclically stops and restarts the application of the coating paste. "As this membrane is much lighter than mechanical valves, very fast reaction times and therefore high speeds are possible," explains Diehm. "Until now, manufacturers were limited to speeds of around 30 to 40 meters per minute. With the new technology, we can achieve up to 150 meters per minute for electrode coating."

In addition to a higher production speed, the elimination of mechanical parts in the application nozzle has other advantages for electrode production: because the membrane can be controlled much more precisely than mechanical valves, production quality is improved and waste is reduced. The technology is now to be transferred from the laboratory to industrial production as part of a spin-off by Ralf Diehm and his team.

Faster drying through systematic process optimization
However, in order for battery production as a whole to benefit from faster electrode coating, the production process must be readjusted in other areas, explains Dr. Philip Scharfer, head of the Thin Film Technology (TFT) group at KIT, who has been researching this topic together with Professor Schabel for many years. "Faster coating requires shorter drying times. Otherwise, the dryer section and therefore the entire system would have to be enlarged accordingly."

Based on fundamental studies of different drying conditions, KIT has already been able to carry out a knowledge-based optimization of the drying process, which reduces the drying time by around 40 percent while maintaining the same electrode properties. In the ProZell II research cluster funded by the Federal Ministry of Education and Research (BMBF), this work is now to be continued together with partners from the Technical University of Braunschweig and the Center for Solar Energy and Hydrogen Research Baden-Württemberg (ZSW) in Ulm.

Celest research platform as a technology driver
Electrode production at record speed combined with high production quality enables considerable cost savings for cell production. Electrodes for up to three times as many battery cells can be produced on a typical production line, helping to meet the growing demand for electromobility. TFT develops its technologies for electrode production - including for future new material systems - as part of the Center for Electrochemical Energy Storage Ulm & Karlsruhe (Celest), one of the world's largest research platforms in the field of battery research. New findings on production technology also flow directly into the Post Lithium Storage (PoliS) Cluster of Excellence, in which KIT is developing the batteries of the future together with the University of Ulm. as

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